NMR evidence for very slow carrier density fluctuations in the organic metal (TMTSF)2_2ClO4_4

We have investigated the origin of the large increase in spin-echo decay rates for the $^{77}$Se nuclear spins at temperatures near to $T=30K$ in the organic superconductor (TMTSF)$_2$ClO$_4$. The measured angular dependence of $T_2^{-1}$ demonstrates that the source of the spin-echo decays lies with carrier density fluctuations rather than fluctuations in TMTSF molecular orientation. The very long time scales are directly associated with the dynamics of the anion ordering occurring at $T=25K$, and the inhomogeneously broadened spectra at lower temperatures result from finite domain sizes. Our results are similar to observations of line-broadening effects associated with charge-ordering transitions in quasi-two dimensional organic conductors.Comment: 5 pages, 4 figure

The Fulde-Ferrell-Larkin-Ovchinnikov State in the Organic Superconductor k-(BEDT-TTF)2Cu(NCS)2 as Observed in Magnetic Torque Experiments

We present magnetic-torque experiments on the organic superconductor k-(BEDT-TTF)2Cu(NCS)2 for magnetic fields applied parallel to the 2D superconducting layers. The experiments show a crossover from a second-order to a first-order transition when the upper critical field reaches 21 T. Beyond this field, which we interpret as the Pauli limit for superconductivity, the upper critical field line shows a pro-nounced upturn and a phase transition line separates the superconducting state into a low- and a high-field phase. We interpret the data in the framework of a Fulde-Ferrell-Larkin-Ovchinnikov state.Comment: 2 pages, 1 figur

Inhomogeneous electronic structure probed by spin-echo experiments in the electron doped high-Tc superconductor Pr_{1.85}Ce_{0.15}CuO_{4-y}

63Cu nuclear magnetic resonance (NMR) spin-echo decay rate (T_2^{-1}) measurements are reported for the normal and superconducting states of a single crystal of Pr_{1.85}Ce_{0.15}CuO_{4-y} (PCCO) in a magnetic field B_0=9T over the temperature range 2K<T<200K. The spin-echo decay rate is temperature-dependent for T<55K, and has a substantial dependence on the radio frequency (rf) pulse parameters below T~25K. This dependence indicates that T_2^{-1} is strongly effected by a local magnetic field distribution that can be modified by the rf pulses, including ones that are not at the nuclear Larmor frequency. The low-temperature results are consistent with the formation of a static inhomogeneous electronic structure that couples to the rf fields of the pulses.Comment: 4 pages, 4 figure

An Approach to Measuring Step Excrescence Effects in the Presence of a Pressure Gradient

An experimental study was undertaken to determine the effects of step excrescences on boundary layer transition using a unique ground test facility in which the test model was propelled though still air. The models used were designed to have a nominally constant pressure gradient so that the results would be relevant to laminar flow aircraft whose wings often have long runs of mildly favorable pressure gradient. The models had an integrated continuously adjustable two-dimensional step, which could be adjusted to be forward-facing or aft-facing. The large model was used to increase the Reynolds numbers examined so that the results are applicable to laminar flow flight vehicles. Multiple measurement methods, including Preston tubes, hot wires, accelerometers, a boundary layer traverse, and static pressure taps were used to provide comparison data, and to add to the physical understanding of the results. The propelled-model test approach required that the instrumentation be self-contained and ride along with the model as the carrier vehicle moved down the test track. Due to the relatively short times available for data-taking (approximately 15-30 seconds per run), the initialization and data analysis techniques had to be tailored for this application

Mechanism for the Singlet to Triplet Superconductivity Crossover in Quasi-One-Dimensional Organic Conductors

Superconductivity of quasi-one-dimensional organic conductors with a quarter-filled band is investigated using the two-loop renormalization group approach to the extended Hubbard model for which both the single electron hopping t_{\perp} and the repulsive interaction V_{\perp} perpendicular to the chains are included. For a four-patches Fermi surface with deviations to perfect nesting, we calculate the response functions for the dominant fluctuations and possible superconducting states. By increasing V_{\perp}, it is shown that a d-wave (singlet) to f-wave (triplet) superconducting state crossover occurs, and is followed by a vanishing spin gap. Furthermore, we study the influence of a magnetic field through the Zeeman coupling, from which a triplet superconducting state is found to emerge.Comment: 11 pages, 15 figures, published versio

Pre-M Phase-promoting Factor Associates with Annulate Lamellae in Xenopus Oocytes and Egg Extracts

We have used complementary biochemical and in vivo approaches to study the compartmentalization of M phase-promoting factor (MPF) in prophase Xenopus eggs and oocytes. We first examined the distribution of MPF (Cdc2/CyclinB2) and membranous organelles in high-speed extracts of Xenopus eggs made during mitotic prophase. These extracts were found to lack mitochondria, Golgi membranes, and most endoplasmic reticulum (ER) but to contain the bulk of the pre-MPF pool. This pre-MPF could be pelleted by further centrifugation along with components necessary to activate it. On activation, Cdc2/CyclinB2 moved into the soluble fraction. Electron microscopy and Western blot analysis showed that the pre-MPF pellet contained a specific ER subdomain comprising "annulate lamellae" (AL): stacked ER membranes highly enriched in nuclear pores. Colocalization of pre-MPF with AL was demonstrated by anti-CyclinB2 immunofluorescence in prophase oocytes, in which AL are positioned close to the vegetal surface. Green fluorescent protein-CyclinB2 expressed in oocytes also localized at AL. These data suggest that inactive MPF associates with nuclear envelope components just before activation. This association may explain why nuclei and centrosomes stimulate MPF activation and provide a mechanism for targeting of MPF to some of its key substrates

Influência das variáveis solvente, temperatura e tempo na extração de compostos fenólicos totais em sementes de maracujá gerada no processamento industrial.

O objetivo deste trabalho consistiu em quantificar o teor de compostos fenólicos totais no sentido de agregar valor funcional e nutricional a este resíduo agroindustrial e avaliar a influência dos variáveis tipos de solvente, tempo e temperatura na extração destes compostos.Edição dos Anais do 12º Congresso Nacional da Sociedade Brasileira de Alimentação e Nutrição, Foz do Iguaçu, PR, 13 a 16 de agosto de 2013